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constant enthalpy or entropy in PSV sizing?

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wormhhh

Chemical
Dec 22, 2005
21
Hi,there:

Would you handle the prossure relief process through the valve as an isenthalpy or an isentropy process? Please give some reference if possible. Same questions to control valve. Many thanks.
 
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The gas is being throttled. The enthalpy is constant, but the internal energy is not necessarily constant. This may result in a temperature change through the valve. Look up information on the Joule-Thompson effect to better explain this.
 
Most of what I have read on the subject is to prefer treating it as an isentropic process although the isenthalpic approach is condidered acceptable. I think the isentropic process assumes all the energy of expansion goes into to kinetic energy. The isenthalpic process implies a some transfer of "expansion energy" to random heat. So, I would think that the isenthalpic process underpredicts the theoretical maximum flux.

The isentropic process, in theory, occurs in an ideal nozzle.
However, we generally assume that a gas expanding through an orifice in a pipeline is isenthalpic. PSVs seemed to be a combination of both.

 
Wormhhh,

I was involved with a similar discussion some time past. The discussion started about the outlet piping but also covers what happens in the PSV. Have a look at this thread...
thread408-63173

Hope this helps.
 
Everything I have ever seen on the topic indicates that the process is isenthalpic and essentially adiabatic.
 
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