You will find it easier to work in specific humidity rather than relative humidity. Deduct specific humidity of incoming air from your desired level and divide that into the steam weight. If you work in gm/m3 then your answer is in m3.
I would suggest that you visit the Grundfos web site where you can download the pump curves and details of their pressure controllers. The beauty of their system is that it all fits together. Simply wire the control to the module in the pump.
We use this system for pressure and secondary...
The photograph shows that the chimney with the strakes is free standing whilst the others are guyed.
The strakes are fitted to shed turbulence caused by other obstructions but they are only required on free standing stacks.
The jury is out on how effective they are.